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According to Amsoil:
0W-30, 5W-30 and 10W-30 synthetic motor oils are ALL 30 weight oils. The answer is that ANY one can be used regardless if your vehicle owners manual says to use, for example, a 5W-30. "W" means winter. In winter weather the 0W oil will flow like a 0W oil, and the 5W will flow like a 5W oil and a 10W will flow like a 10W oil just until the engine warms up. In order to understand the differences one has to first understand that the numerical values given to these various weight oils are strictly empirical numbers. For example, 0W does not mean that the oil has no weight. That is one of the reasons why we say it is strictly an empirical number.
In order to determine the differences between the three oils one has to look at the kinematic viscosity of each lubricant. The kinematic viscosity is essentially the amount of time, in centistokes, that it takes for a specified volume of the lubricant to flow through a fixed diameter orifice at a given temperature.
So w is winter!
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