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basically, the first number is the weight of the oil when it's cold... and the 2nd number is what weight when it's operating at 100C
This is from wikipedia
Grades of motor oil
Single-grade motor oil
The Society of Automotive Engineers, usually abbreviated as SAE, has established a numerical code system for grading motor oils according to their kinematic viscosity. For single-grade oils, the kinematic viscosity is measured at a reference temperature of 100 °C (212 °F) in units of mm²/s or the equivalent older non-SI units, centistokes (abbreviated cSt). Based on the range of viscosity the oil falls in at that temperature, the oil is graded as an SAE number 0, 5, 10, 20, 30, 40, 50, 60 or 70. The higher the viscosity, the higher the SAE grade number is. These numbers are often referred to as the weight of a motor oil. The reference temperature is meant to approximate the operating temperature to which motor oil is exposed in an engine.
The viscosity of single-grade oil derived from petroleum unimproved with additives changes considerably with temperature. As the temperature increases, the viscosity of the oil decreases logarithmically in a relatively predictable manner. On single-grade oils, viscosity testing can be done at cold winter (W) temperature (as well as checking minimum viscosity at 100 °C or 212 °F) to grade an oil as SAE number 0W, 5W, 10W, 15W, 20W, or 25W. A single-grade oil graded at the hot temperature is expected to test into the corresponding grade at the winter temperature; i.e. a 10 grade oil should correspond to a 10W oil. For some applications, such as when the temperature ranges in use are not very wide, single-grade motor oil is satisfactory; for example, lawn mower engines.
Multi-grade motor oil
The temperature range the oil is exposed to in most vehicles can be wide, ranging from cold ambient temperatures in the winter before the vehicle is started up to hot operating temperatures when the vehicle is fully warmed up in hot summer weather. The difference in viscosities for any single-grade oil is too large between the extremes of temperature. To bring the difference in viscosities closer together, special polymer additives called viscosity index improvers are added to the oil. These additives make the oil a multi-grade motor oil. The viscosity of a multi-grade oil still varies logarithmically with temperature, but the slope representing the change is lessened. This slope representing the change with temperature depends on the nature and amount of the additives to the base oil.
The API/SAE designation for multi-grade oils includes two grade numbers; for example, 10W-30 designates a common multi-grade oil. The first number associated with the W is not rated at any single temperature. The "10W" means that this oil can be pumped by your engine as cold as a single-grade 10 weight oil can be pumped. "5W" can be pumped at a lower temperature than "10W". The second number, 30, means that the viscosity of this multi-grade oil at 100°C (212°F) operating temperature corresponds to the viscosity of a single-grade 30 oil at same temperature. The governing SAE standard is called SAE J300. The motor oil grade and viscosity to be used in a given vehicle is specified by the manufacturer of the vehicle.
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